The replacement battery via Amazon, seems to work OK; I can now press the button on the unit and the "flashlight" works for the first time since I've owned it.
I did have to cut off the V100's battery connector and solder it to the new battery's leads, as the battery I'd purchased came with a JST PH2.0mm connector which is ~2x the size of the V100's! I think the V100 battery's wires are the smallest insulated wires I've ever soldered.
Measuring voltage at the battery disconnected = 4.03v
With it connected to the V100, and the V100 powered via USB, = 4.13v
So, it's charging the battery when it's powered.